Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine

Cheung, Kwong Chak; Guo, Peng; So, Ming-Him; Lee, Yoon Suk; Ho, Kin‐Yip; Wong, Wing‐Leung; Lee, Kam-Han; Wong, Wing‐Tak; Zhou, Zhóngyuan; Wong, K.P.

doi:10.1016/j.jorganchem.2009.04.034

Cited by 31 publications

(29 citation statements)

References 25 publications

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“…These results show that the complex on the surface of an electrode in the presence of acid is more effective for CO 2 reduction compared to the homogenous catalytic system. Also, in comparison to the heterogeneous reaction by only casting the complex on the surface of the electrode with other reported studies, including polymerization of complexes on the surface of electrode [20][21][22], this method is much easier and only needs a small amount of the complex. Table 2 shows the reduction potentials of the various complexes (potentials in V versus Fc/Fc + ) for the electrocatalytic reduction of CO 2 [32].…”

Section: Catalytic Activity Of the Complex As A Heterogeneous Catalystmentioning

confidence: 99%

“…Several Re complexes have high selectivity for the reduction of CO 2 in the presence of protons [18,19]. Electrocatalytic reactions in the presence of metal complexes have been investigated in detail for homogenous catalysis in a solution or heterogeneous catalysis at the surface of a coated electrode with polymerized complexes [14,[20][21][22].…”

Section: Introductionmentioning

confidence: 99%

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Electrocatalytic reduction of CO2 using the dinuclear rhenium(I) complex [ReCl(CO)3(μ-tptzH)Re(CO)3]

et al. 2015

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Section: Catalytic Activity Of the Complex As A Heterogeneous Catalystmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Electrocatalytic reduction of CO2 using the dinuclear rhenium(I) complex [ReCl(CO)3(μ-tptzH)Re(CO)3]

et al. 2015

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“…In continuation of our ongoing research on the field of rhenium coordination compounds, the title compound was synthesized and its molecular and crystal structure were elucidated. Thecrystal structures of several other rhenium coordination compounds featuring the bipyridylamine core in the ligand sphere are apparent in the literature [3][4][5][6][7]. The title compound is arhenium(I) coordination compound.…”

Section: Discussionmentioning

confidence: 99%

Crystal structure of tricarbonyl-chlorido-(N-(pyridin-2-yl)-N-((4-tertbutyl) benzoyl)pyridine-2-amine)rhenium(I), C24H21ClN3O4Re

Mukiza

Gerber

Hosten

et al. 2015

Zeitschrift Für Kristallographie - New Crystal Structures

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Source of materialThecompoundwas obtained upon reacting Re(CO) 5 Cl with the ligand in amixture of toluene and ethanol. Crystals suitable for the diffraction study were obtained upon free evaporation of the solvent. Experimental detailsCarbon-bound Hatomswere placed in calculated positions (C-H 0.95 Å) and were included in the refinement in the riding model approximation, with U iso (H) setto1.2U eq (C). The Hatoms of the methyl groups were allowed to rotate with afixed angle around the C-C bond to best fit the experimental electron density (HFIX 137 in the SHELX program suite [13]), with U iso (H) sett o 1.5U eq (C). Only 96%completeness was achieved. DiscussionNext to cardiovascular diseases, cancer has become one of the main fatal diseases in industrialized countries. Apart from classicalsurgery,chemo-and radiotherapeutic treatments have entered the arsenal of possible cures for certain types of cancer. All methods, however, suffer from theirown setofproblematic side-effects and, as ac onsequence, the development of radiopharmaceuticals -combining the advantages of chemotherapy as well as radiation methods while at the sametimeavoiding their unique respective undesiredside-effects -has been atopic of research [1,2].T ailoring andf ine-tuning of thee nvisionedr adiopharmaceuticals' properties such as lipophilicityand,inparticular, inertness is of paramountimportancewithrespect to possible future in vivo applications in contemporary medicine and requires sound knowledge about structural parameters of the ligands applied if a more heuristic approach in the synthesis is to triumph over pure trial-and-error as it is encountered in this specific field of coordination chemistry up to the present day. In addition, the spatial requirements of pharmaceuticals are of importance as this factor influences on their interaction with enzymatic systems and, as a consequence,t he pathway and rate of conjugation, functionalization and secretion from the body. In continuation of our ongoing research on the field of rhenium coordination compounds, the title compound was synthesized and its molecular and crystal structure were elucidated. Thecrystal structures of several other rhenium coordination compounds featuring the bipyridylamine core in the ligand sphere are apparent in the literature [3][4][5][6][7]. The title compound is arhenium(I) coordination compound. Thec entrala tom is hexacoordinate. The octahedral coordination sphere is comprised of one chlorine atom and three carbonyl groups in fac configuration as well as ab identate bipyridylamine-derived ligand. The coordination of the latter is effected by the two nitrogen atomso ft he pyridylm oieties. A conformational analysis of thes ix-memberedc helate ring accordingtoCremer&Pople [8]shows the latter to adopt a B 4,1 conformation on the rhenium atom as well as one nitrogen atom (B N3,Re1 ) [9]. The Re-Cl bond length was measured at 2.4717(6) Å. The Re-C bond lengths vary only slightly and cover arange of 1.901(3)-1.915(3) Å. In comparison to other rhenium(I) tricarbonyl c...

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“…[32] A dipyridylamine ligand with ap endant pyrrole (N-(3-N,N'-bis(2pyridyl)propylamino)pyrrole (PPP)) wasu sed to prepare aR e I complex, namely,[ Re(CO) 3 (k 2 -N,N-PPP)Cl]. [32] A dipyridylamine ligand with ap endant pyrrole (N-(3-N,N'-bis(2pyridyl)propylamino)pyrrole (PPP)) wasu sed to prepare aR e I complex, namely,[ Re(CO) 3 (k 2 -N,N-PPP)Cl].…”

Section: Metal Complexesmentioning

confidence: 99%

“…In addition to cobalt complexes, rheniumc omplexes are also reported to be selective towardC Od uring the CO 2 RR. [32] A dipyridylamine ligand with ap endant pyrrole (N-(3-N,N'-bis(2pyridyl)propylamino)pyrrole (PPP)) wasu sed to prepare aR e I complex, namely,[ Re(CO) 3 (k 2 -N,N-PPP)Cl]. Reductionw as carried out on ag lassyc arbon (GC) electrodew ith poly[Re(-CO) 3 (k 2 -N,N-PPP)Cl]f ilm prepared throughe lectrochemical polymerization of the pyrrole (Py) moiety.The resulting catalyst exhibited electrocatalytic activity for the reduction of CO 2 to CO.…”

Section: Metal Complexesmentioning

confidence: 99%

Role of Organic Components in Electrocatalysis for Renewable Energy Storage

Liu

Bai

Zhang

et al. 2018

Chemistry A European J

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Carbon dioxide electroreduction and water splitting are known as two promising strategies to convert renewable intermittent electrical energy into chemical energy. Thus, the three half-reactions, namely, CO reduction reaction, hydrogen evolution reaction, and the oxygen evolution counter reaction, in these two electrolytic processes have attracted wide research interest. Organic polymer electrocatalysts or electrocatalysts containing organic components play important roles in these catalytic processes. It has been shown that the organic molecules can efficiently catalyze the reactions themselves, and modulate the active sites towards high selectivity and efficiency. The roles of the organic molecules in conducting polymers, the metal complexes, and the framework materials are extracted for the three half-reactions mentioned above, and this comprehensive review will serve as a guide for future research and aid in the design of electrocatalysts related to organic molecules.

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Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine

Cited by 31 publications

References 25 publications

Electrocatalytic reduction of CO2 using the dinuclear rhenium(I) complex [ReCl(CO)3(μ-tptzH)Re(CO)3]

Electrocatalytic reduction of CO2 using the dinuclear rhenium(I) complex [ReCl(CO)3(μ-tptzH)Re(CO)3]

Crystal structure of tricarbonyl-chlorido-(N-(pyridin-2-yl)-N-((4-tertbutyl) benzoyl)pyridine-2-amine)rhenium(I), C24H21ClN3O4Re

Role of Organic Components in Electrocatalysis for Renewable Energy Storage

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