2024
DOI: 10.21203/rs.3.rs-4369935/v1
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Electrochemical and spectroscopic analyses for praseodymium complexes in potassium bis(trifluoromethylsulfonyl)amide melts

Masahiko Matsumiya,
Takumi Mishima,
Shun Tokumitsu
et al.

Abstract: In this study, the electrochemical behavior of praseodymium complex; Pr(III) in potassium bis(trifluoromethyl-sulfonyl) amide; K[NTf2] melts was under investigation. There is speculation that the first peak of reduction at + 2.27 V is probably Pr(IV) formation. The electrochemical analysis revealed that the electrodeposition reaction of Pr(III) to Pr(0) would cause the reduction peak of Pr(III) at + 0.87 V at 488 K. By semi-integral and semi-differential analysis, the diffusion coefficient and activation energ… Show more

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