2001
DOI: 10.1016/s0020-1693(01)00463-7
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Electrochemical and spectroscopic characterization of new cobalt(II) complexes. Catalytic activity in oxidation reactions by molecular oxygen

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Cited by 45 publications
(44 citation statements)
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“…The location of the H atoms showed unequivocally that (I) occurs in the enol±imino form in the crystalline state, in agreement with previous IR results ( Kruger et al, 2001;Pui et al, 2001). This is also the form found in CHCl 3 solution (Yoshida et al, 2000;Kruger et al, 2001).…”
Section: Commentsupporting
confidence: 91%
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“…The location of the H atoms showed unequivocally that (I) occurs in the enol±imino form in the crystalline state, in agreement with previous IR results ( Kruger et al, 2001;Pui et al, 2001). This is also the form found in CHCl 3 solution (Yoshida et al, 2000;Kruger et al, 2001).…”
Section: Commentsupporting
confidence: 91%
“…The title compound, (I), has been shown to form helicate supramolecular complexes of the form [M 2 L 2 ] with transition metals (Yoshida & Ichikawa, 1997;Yoshida et al, 2000;Kruger et al, 2001). Free N-salicylideneanilines are often thermochromic (Ogawa et al, 1998;Filarowski et al, 2002;Popovic  et al, 2002;Ogawa & Harada, 2003) due to a temperature-dependent equilibrium between the keto±amine and enol±imino forms.The location of the H atoms showed unequivocally that (I) occurs in the enol±imino form in the crystalline state, in agreement with previous IR results ( Kruger et al, 2001;Pui et al, 2001). This is also the form found in CHCl 3 solution (Yoshida et al, 2000;Kruger et al, 2001).…”
supporting
confidence: 91%
“…Their I pa /I pc ratios increase with increasing sweep rate, converging to 1, suggesting quasireversible redox systems [61,62] (Table 3). These results are consistent with the electronic effects due to the substituents such as methyl and chlorine grafted on the H 2 Salen [22][23][24][25]47].…”
Section: Complexessupporting
confidence: 84%
“…The ligands were prepared as previously reported in the literature [1,[22][23][24][25]. 60 mg (1 mmol) of diaminoethane in EtOH (8 cm 3 ) was added dropwise to 244 mg (2 mmol) of salicylaldehyde or its derivatives (EtOH, 12 cm 3 ).…”
Section: Syntheses Of the Ligandsmentioning
confidence: 99%
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