Electrochemical and spectroscopic studies of cobalt-hexacyanoferrate film modified electrodes

Electrooxidation of sulfide by cobalt pentacyanonitrosylferrate film on glassy carbon electrode by cyclic voltammetry

“…According to the literature [17,31], Co 2+ ions in the modified films do not undergo oxidation, and the formation of Co 3+ in aromatic compounds with cyanoferrate anions is very unlikely due to its instability. Therefore, the mechanism that defines the process in the redox couple of CoPCNF on the GC electrode is described by Eq.…”

Electrochemical behavior of iodide at a nickel pentacyanonitrosylferrate film modified aluminum electrode prepared by an electroless procedure

“…In the surface reaction of transition metal hexacyanoferrate films, the role of cations is more important than that of the anions [27]. The electrochemical behavior of the modified electrode may be indicative of some characteristics of the film depending on the nature or size of the alkali-metal cations.…”

Solvent effects on the solid-state electrochemistry of samarium (III) hexacyanoferrate (II)

“…For example, PB shows permeability in the order of K + > Na + > Li + , similarly to the order of the radii of hydrated ions of Li + , Na + and K + whose values are 0.12, 0.18 and 0.235 nm [52], respectively. Gao et al [53] reported a permeability order of K + > Na + > Li + for CoHCF; our previous results also indicated that the permeability of CoHCF is K + > Na + > Li + [10,11]. Engel and Grabner [54] reported the permeability order of CuHCF as K + > Na + , Kulesza and Faszynska [55] and Dong and Jin [56] showed that the permeability order of InHCF is also K + > Na + .…”