Electrochemical Behaviour of (n‐Bu4N)4[AsVMo11O40] and (n‐Bu4N)4[AsV2Mo10O40] Doped PEDOT Film and Its Quartz Crystal Microbalance Studies
Indherjith Sakthinathan,
Tadaharu Ueda,
Timothy McCormac
Abstract:Keggin‐type polyoxometalates (POMs), (n‐Bu4N)4[AsVMo11O40] (AsVMo11) and (n‐Bu4N)4H[AsV2Mo10O40] (AsV2Mo10), have been immobilised with the conducting polymer poly (3,4‐ethylenedioxythiophene) (PEDOT) on the surface of the glassy carbon electrode via chronocoulometry technique. The voltammetric behaviour of these modified electrodes was investigated with cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM). The resulting films showed the surface adsorbed behaviour and dependence on the pH … Show more
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