2000
DOI: 10.1016/s0378-7753(00)00448-1
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Electrochemical characteristics of Mg–Ni alloys as anode materials for secondary Li batteries

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Cited by 48 publications
(38 citation statements)
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“…On subsequent cycling, two cathodic and anodic peaks were observed corresponding to the two step lithiation and delithiation process. The cathodic peak at 0.25 V was due to the lithiation of MgS and that observed at 0.005 V was due to the alloying of Li with Mg that is formed during the reduction of MgS [32][33][34]. From previous studies, alloying of Li with Mg is proved to occur below 0.1 V vs Li/Li + in anode materials like pure Mg [33], Mg-Ni Fig .…”
mentioning
confidence: 83%
“…On subsequent cycling, two cathodic and anodic peaks were observed corresponding to the two step lithiation and delithiation process. The cathodic peak at 0.25 V was due to the lithiation of MgS and that observed at 0.005 V was due to the alloying of Li with Mg that is formed during the reduction of MgS [32][33][34]. From previous studies, alloying of Li with Mg is proved to occur below 0.1 V vs Li/Li + in anode materials like pure Mg [33], Mg-Ni Fig .…”
mentioning
confidence: 83%
“…Kim and coworkers [147] have studied the lithiation of pure Mg. They have obtained a capacity of 3070 mAh/g for the first lithiation (probably going deep into the β phase region) and 2150 mAh/g for the first delithiation.…”
Section: Magnesiummentioning
confidence: 99%
“…However, graphite anodes have lower volumetric energy density and hinder performance improvements of lithium ion batteries 1) . Consequently, anode materials that feature high volumetric energy density such as silicon 2) , magnesium 3) , aluminum 4) and tin 5) are being researched today. Magnesium-based anodes have many advantages, including low mass density, high workability, low cost and a very high theoretical capacity up to 3350 mAhg −1 .…”
Section: Introductionmentioning
confidence: 99%