“…In term of heteroatoms doped carbons, some nonmetallic elementals including N, B, S and P [9][10][11][12], can be employed as dopants to modulate the surface feature, energy band structure to improve the application performances. As an intimate neighbor of C in periodic label, N is the most feasible dopant for the conjugation of its lone-pair electrons with the delocalized system of graphitic carbon network with minimal lattice distortion as a sequence of the rich electrons feature of N and the similar atomic radius to C. As for N doped carbons (NCs), the N forms play vital roles on the electronic structure and surface properties of C-N framework, for instance, pyridinic-and pyrrolic-typed N located at the rim of the C-N network facilitate higher capacitive performance via pseudocapacitance contribution owing to the susceptibility to oxidation [13,14]; whereas the graphitic N by replacing skeletal C is beneficial for a higher conductivity owing to the electron donating nature [15]; additionally, the increased surface polarity because of the electronegativity difference between N and C enhances the hydrophilicity [16,17], which is also vital for higher capacitive performance.…”