Electrochemical conversion of CO₂ to syngas with a stable H₂/CO ratio in a wide potential range over ligand-engineered metal–organic frameworks

Abstract

Zn-BTC survived reconstruction with the possession of slightly reduced Zn2+ and carboxyl groups at negative potential, resulting in a steady H2/CO ratio (∼1 : 2) in a wide potential window (−0.96 to −1.96 V vs. RHE).

Thermocatalytic Conversion of CO2 to Valuable Products Activated by Noble‐Metal‐Free Metal‐Organic Frameworks

“…Metal‐organic frameworks (MOFs), a class of new catalysts that constructed from metal ions/clusters and organic ligands through coordination bonds, have attracted much attention in the field of catalysis [19–41] . Many important researches focused on hydrogenation, [42–45] reduction, [46–51] cycloaddition, [52–56] carboxylation, [57–59] and coupling reactions [60–63] have been reported in recent years.…”

A copper coordination polymer precatalyst with asymmetric building units for selective CO2-to-C2H4electrolysis

“…The electrochemical CO 2 reduction reaction (CO 2 RR) resulting in valuable industrial feedstocks under ambient conditions is considered as a desirable avenue to simultaneously alleviate climate problems and realize articial carbon neutralization. [1][2][3][4][5] For CO 2 RR products (e.g., carbon monoxide, formate, methane, ethylene, ethanol, etc. ), ethylene (C 2 H 4 ) has been desired in recent years because of its high economic and practical value.…”

Thermocatalytic Conversion of CO2 to Valuable Products Activated by Noble‐Metal‐Free Metal‐Organic Frameworks

“…Metal‐organic frameworks (MOFs), a class of new catalysts that constructed from metal ions/clusters and organic ligands through coordination bonds, have attracted much attention in the field of catalysis [19–41] . Many important researches focused on hydrogenation, [42–45] reduction, [46–51] cycloaddition, [52–56] carboxylation, [57–59] and coupling reactions [60–63] have been reported in recent years.…”