Electrochemical corrosion characteristics of phosphated S355J2 steel in sulfate environment

Abstract

Large number of mechanical and chemical surface pretreatment techniques is actually used on steels in industrial practice. Choosing the right combination of these technologies is one of the most important tasks for many applications. The purpose of this research was to evaluate the influence of selected mechanical surface preparation methods (grinding, sandblasting) on the quality and electrochemical corrosion characteristics of S355J2 steel before and after the final chemical surface treatment by the technology of manganese phosphating. The surface morphology of the formed phosphate layer was evaluated by a scanning electron microscopy (SEM) and the cross section analysis was performed by a light metallographic microscopy. 0.1M Na2SO4 solution simulating aggressive industrial pollution was selected for electrochemical corrosion tests. Impact evaluation of various mechanical and chemical surface treatments on the corrosion properties of the tested steel was realized by potentiodynamic polarization tests (PD) and electrochemical impedance spectroscopy (EIS) using the Tafel analysis and equivalent circuits method respectively. The obtained results proved that sandblasting negatively affected the corrosion resistance of S355J2 steel and subsequently created manganese phosphate layer.

Effects of TiO2Addition on the Electrochemical Performance of the Overlay Welded High-manganese Steel Cladding

“…In other words, it means a pure or ideal capacitive response [10]. Figure 4 shows equivalent circuit best describing the electrochemical processes [11]. In this equivalent model, Rs is the solution resistance; Rp stands for the resistance of the sample in the solution, and CPE1 counts for the constant phase element corresponding to the capacitance of the corrosion pits.…”