“…The minisensor developed has been successfully validated for soil using simulated and real field samples. The detection limit achieved with the sensor (at S/N ¼ 3) for soil extracts was 2.1 mg/L, significantly lower that the detection limits reported for spectroscopic (Sreekumar et al, 2003;Ensafi et al, 2004;L opez Pasquali et al, 2010), chromatographic (Michalski and Kurzyca, 2006;Niedzielski et al, 2006;Kodamatani et al, 2011) and electrochemical (Salimi et al, 2008;Pietrzak and Meyerhoff, 2009;Pham et al, 2011) approaches. Biosensor systems for nitrites have been also suggested in literature (Chen et al, 2009;Liu et al, 2009;Silveira et al, 2010;Tepper, 2010) with comparable detection limits.…”