2008
DOI: 10.1016/j.bios.2008.06.007
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Electrochemical determination of antioxidant capacities in flavored waters by guanine and adenine biosensors

Abstract: a b s t r a c tThe immobilization and electro-oxidation of guanine and adenine as DNA bases on glassy carbon electrode are evaluated by square wave voltammetric analysis. The influence of electrochemical pretreatments, nature of supporting electrolyte, pH, accumulation time and composition of DNA nucleotides on the immobilization effect and the electrochemical mechanism are discussed. Trace levels of either guanine or adenine can be readily detected following short accumulation time with detection limits of 35… Show more

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Cited by 50 publications
(23 citation statements)
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“…The correlation between AOP assay and total polyphenols had an R 2 =0.7464. If we compare these results with those obtained by Kamel et al [1], it can be observed that they are similar in spite of the different methodology used. They applied an electrochemical method in which they used a biosensor of guanine and adenine [1].…”
supporting
confidence: 48%
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“…The correlation between AOP assay and total polyphenols had an R 2 =0.7464. If we compare these results with those obtained by Kamel et al [1], it can be observed that they are similar in spite of the different methodology used. They applied an electrochemical method in which they used a biosensor of guanine and adenine [1].…”
supporting
confidence: 48%
“…If we compare these results with those obtained by Kamel et al [1], it can be observed that they are similar in spite of the different methodology used. They applied an electrochemical method in which they used a biosensor of guanine and adenine [1]. In their work, the results ranged from 1.6 and 8.0 mg ascorbic acid/l (0.01 and 0.05 mM ascorbic acid or VCEAC).…”
supporting
confidence: 48%
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“…Several electrochemical biosensors with immobilized layer of DNA have been reported for the determination of electroactive and non-electroactive compounds interacting with DNA, detection of specific sequence of DNA and monitoring of DNA integrity 11 . These findings have directed the applications of DNA biosensors in clinical diagnostics, forensic and biomedical applications.…”
Section: Current Scenariomentioning
confidence: 99%
“…Independently the working electrodes with chemically modified surfaces have been developed. Modification of carbon electrodes [8,59,60], carbon-paste electrodes [38,61] or polypyrrol electrode [62,63] were described for determination of antioxidants in various types of samples, most often using the complex of nickel phthalocyanine or various polymers. In contrast to chromatography, the electrochemical methods can have the drawback of insufficient selectivity of determination in analyses of antioxidant mixtures.…”
Section: Central European Journal Of Chemistrymentioning
confidence: 99%