Electrochemical discharge machining (ECDM) is a hybrid process comprising of features of both electrochemical machining and electrical discharge machining. The combined features enable ECDM process to expand its applications to conductive and non-conductive materials. In recent years, several attempts have been made to utilize ECDM process for micro-machining of glass, composites, ceramics, steel, super-alloys, etc. The machining behaviour of ECDM process is significantly affected by several process parameters including electrolytic properties, tool electrode, etc. The present research article focuses on environmental aspects of different electrolytes used in ECDM by analysis of fume mass concentration and characterization of fume particles generated during machining. The average size, morphologies and chemical composition of fume particles were studied by field emission scanning electron microscopy and energy-dispersive spectroscopy, respectively. The fume mass concentration increased from 30.35 to 220.76 mg/m 3 , 15.10 to 98.34 mg/m 3 and 40.56 to 290.0 mg/m 3 with increases in electrolyte concentrations from 20 to 50% of NaOH, NaCl and HCl, respectively. The average size of fume particles generated in ECDM process was less than 100 nm. Additionally, the Fourier transform infrared spectroscopy of breathing air revealed the presence of amines, CH 4 , NO 2 , SO 2 , CO 2 , thio compound disulphides and halogenated hydrocarbons in the breathing zone of operator.