Electrochemical performance of a lead fluoride electrode mixed with carbon in an electrolyte containing triphenylboroxine as an anion acceptor for fluoride shuttle batteries

Konishi, Hiroaki; Minato, Taketoshi; Abe, Takeshi; Ogumi, Zempachi

doi:10.1016/j.matchemphys.2019.01.006

Cited by 27 publications

(38 citation statements)

References 31 publications

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“…[307] Reversible reactions based on fluorideion transfer have been proven for the BiF 3 and PbF 2 electrodes. [308,309] However,d issolution of the active material in this kind of electrolyte led to ap oor cycling performance. Recently,Davis et al pushed toward room-temperature FIBs by developing al iquid fluoride-ion-conducting electrolyte with anhydrous tetraalkylammonium fluoride (e.g.…”

Section: Fluoride-ion Batteriesmentioning

confidence: 99%

Halide‐Based Materials and Chemistry for Rechargeable Batteries

et al. 2020

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Rechargeable batteries are considered one of the most effective energy storage technologies to bridge the production and consumption of renewable energy. The further development of rechargeable batteries with characteristics such as high energy density, low cost, safety, and a long cycle life is required to meet the ever‐increasing energy‐storage demands. This Review highlights the progress achieved with halide‐based materials in rechargeable batteries, including the use of halide electrodes, bulk and/or surface halogen‐doping of electrodes, electrolyte design, and additives that enable fast ion shuttling and stable electrode/electrolyte interfaces, as well as realization of new battery chemistry. Battery chemistry based on monovalent cation, multivalent cation, anion, and dual‐ion transfer is covered. This Review aims to promote the understanding of halide‐based materials to stimulate further research and development in the area of high‐performance rechargeable batteries. It also offers a perspective on the exploration of new materials and systems for electrochemical energy storage.

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Section: Fluoride-ion Batteriesmentioning

confidence: 99%

Halide‐Based Materials and Chemistry for Rechargeable Batteries

et al. 2020

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“…The electrochemical discharge and charge curves of (A) pulverized PbF 2 and (B) pulverized PbF 2 mixed with carbon. (C) The optimized molecular structure of TPhBX (reproduced from Reference [51]. Copyright [2019] Elsevier)…”

Section: Dissolution/deposition Type Fibsmentioning

confidence: 99%

Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes: A review

Kaleibari

2022

Intl J of Energy Research

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Summary Fluorine, as the most electronegative element, provides the highest electrode potential when it undergoes redox reactions. Moreover, fluoride ion is intrinsically an excellent charge carrier in both electrolytes and electrode structures owing to its small size, low atomic weight, and good ionic mobility. Hence, batteries based on fluorine electrochemistry, the so‐called fluoride ion batteries (FIBs), have recently been deemed as an alternative next‐generation high energy density battery system. This article reviews the recent progress in FIBs based on liquid electrolytes. The mechanisms, advantages, and drawbacks of FIBs are discussed. In the end, the perspective illuminating the research directions for further development is presented.

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“…[307] Reversible Reaktionen basierend auf Fluorid-Ionen-Transfer wurden für die BiF 3 -und PbF 2 -Elektroden nachgewiesen. [308,309] Lçsungsmittel Bis(2,2,2-trifluorethyl)ether (BTFE)) verwendeten. [310] Dieser Elektrolyt zeigt eine ro-…”

Section: Angewandte Chemieunclassified

Halogenid‐basierte Materialien und Chemie für wiederaufladbare Batterien

et al. 2020

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Wiederaufladbare Batterien gelten als eine der effektivsten Energiespeichertechnologien, die die Überleitung zwischen der Erzeugung und dem Verbrauch erneuerbarer Energien schafft. Die weitergehende Entwicklung wiederaufladbarer Batterien mit Eigenschaften wie hohe Energiedichte, Kostengünstigkeit, Sicherheit und eine lange Lebensdauer muss dabei die stetig zunehmenden Energiespeicheranforderungen erfüllen. Dieser Aufsatz zeigt den wissenschaftlichen und technologischen Fortschritt wiederaufladbarer Batterien auf, der durch Halogenid‐basierten Materialien und Chemikalien zustande kommt, inklusive der Verwendung von Halogenid‐Elektroden, Halogendotierung von Elektroden und/oder Elektrodenoberflächen, Elektrolyt‐Design und Additive, die schnellen Ionen‐Shuttle und stabile Elektroden/Elektrolyt‐Grenzflächen ermöglichen sowie neue Batteriechemie realisieren. Eine Vielzahl von Batteriechemie basierend auf monovalentem Kation‐, multivalenten Kation‐, Anion‐ oder Dual‐Ionen‐Transfer wird beschrieben. Dieser Aufsatz zielt darauf ab, das Verständis von Halogenid‐basierten Materialien und Chemikalien zu fördern und die weitere Forschung und Entwicklung im Bereich hochleistungsfähiger wiederaufladbarer Batterien anzuregen. Er soll außerdem einen Ausblick auf die Nutzung neuer elektrochemischer Energiespeichermaterialien und ‐systeme bieten.

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Electrochemical performance of a lead fluoride electrode mixed with carbon in an electrolyte containing triphenylboroxine as an anion acceptor for fluoride shuttle batteries

Cited by 27 publications

References 31 publications

Halide‐Based Materials and Chemistry for Rechargeable Batteries

Halide‐Based Materials and Chemistry for Rechargeable Batteries

Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes: A review

Halogenid‐basierte Materialien und Chemie für wiederaufladbare Batterien

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