2023
DOI: 10.1002/chem.202301045
|View full text |Cite
|
Sign up to set email alerts
|

Electrochemical Preparation of Sm(II) Reagent Facilitated by Weakly Coordinating Anions

Abstract: Samarium diiodide (SmI2) is widely used as a strong one‐electron reducing agent and is often employed to form C−C bonds in complex systems. Despite their utility, SmI2 and related salts suffer from several drawbacks that render the use of Sm reducing agents in large‐scale synthesis impractical. Here, we report factors influencing the electrochemical reduction of Sm(III) to Sm(II), towards the goal of electrocatalytic Sm(III) reduction. We probe the effect of supporting electrolyte, electrode material, and Sm p… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2024
2024
2024
2024

Publication Types

Select...
3

Relationship

0
3

Authors

Journals

citations
Cited by 3 publications
references
References 50 publications
0
0
0
Order By: Relevance