Electrochemical properties of aryl-modified gold electrodes

Kullapere, Marko; Kozlova, Jekaterina; Matisen, Leonard; Sammelselg, Väinö; Menezes, Hebert A.; Schiffrin, David J.; Tammeveski, Kaido

doi:10.1016/j.jelechem.2009.12.012

Cited by 17 publications

(8 citation statements)

References 68 publications

(107 reference statements)

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“…Although the current is very small, the observation of current in further cycling implies that the formation of PBA layer is not complete after one cycle, and its gradual growth can be expected. Kullapere et al [23] used electrochemical quartz crystal microbalance to observe a total mass change for a Au electrode during 10 repetitive cycles in the presence of 4-bromobenzenediazonium salt. They found that an increase in mass is observed for the first cycle and a gradual mass increase is also observed on further cycling.…”

Section: Grafting Of In Situ Generated Diazonium Cation By Electrochementioning

confidence: 99%

Grafting of phenylboronic acid on a glassy carbon electrode and its application as a reagentless glucose sensor

Morita

Hirayama

Imura

et al. 2011

Journal of Electroanalytical Chemistry

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Phenylboronic acid (PBA) was covalently grafted to the surface of glassy carbon (GC) electrodes using electrochemical reduction of in situ generated diazonium cation. The grafting of GC surfaces was controlled by varying both the concentration of precursor 3-aminophenylboronic acid and the number of potential cycling during the grafting procedure. Cyclic voltammetry (CV) and eletrochemical impedance spectroscopy (EIS) were used to confirm the grafting of the PBA group to the GC surface and formation of multilayer. The barrier properties of the grafted GC electrodes were studied in the presence of a redox probe such as Fe (CN) 3−/4− 6 by CV. Additionally, the resultant PBA multilayer on the GC electrode was applied for glucose detection utilizing the EIS technique in the presence of a redox probe molecule. Then, the complexation ability of the grafted layers with glucose was also confirmed as an increase of total impedance at non-faradic EIS measurement.

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Section: Grafting Of In Situ Generated Diazonium Cation By Electrochementioning

confidence: 99%

Grafting of phenylboronic acid on a glassy carbon electrode and its application as a reagentless glucose sensor

Morita

Hirayama

Imura

et al. 2011

Journal of Electroanalytical Chemistry

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“…The functionalization of surfaces through reaction with diazonium salts is now a widely recognized method. − It has been successfully implemented in various fields such as sensing, − biosensing, , catalysis, , microelectronics, carbon nanotube modification, − batteries, − etc. and could be met nowadays in industrial applications including inks/paints, medical stents, or thin layers in microelectronics .…”

Section: Introductionmentioning

confidence: 99%

Controlled Modification of Polymer Surfaces through Grafting of Calix[4]arene-Tetradiazoate Salts

et al. 2016

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International audienceAn attractive methodology based on diazonium chemistry has been developed for the surface modification of polymers such as polypropylene (PP), polyethylene terephthalate (PET), and polystyrene (PS). The grafting procedure involves the in situ formation of diazoates in basic aqueous solution. The reactivity of calix[4]arene-tetradiazonium salts and a classical aryldiazonium salt was examined through comparative studies on gold and polymer surfaces. The surfaces were analyzed with a combination of techniques such as AFM, XPS, and ellipsometry. The results highlighted the fact that the calix[4]arene molecules are grafted as a robust and uniform monolayer both on gold and polymer surfaces, allowing a fine control over surface modification. Furthermore, the chemical postfunctionalization of the grafted calixarene platforms equipped with carboxylic-pendant groups was successfully performed with either an amine or an alcohol. These results open real possibilities in the controlled immobilization on polymers of a wide variety of molecules of interest such as biomolecules or chromophores and in the tailoring of polymer properties

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“…Considering that there exist several examples of radical grafting of carbon surfaces that also work on metals such as the above mentioned [33][34][35][36], the results obtained in this study could be directly extrapolated to other electrode materials.…”

Section: Introductionmentioning

confidence: 80%

Radical grafting of carbon surfaces by oxidation of 5-nitroindole derived anions

González‐Fuentes

Díaz-Sánchez

Vela

et al. 2012

Journal of Electroanalytical Chemistry

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Electrochemical properties of aryl-modified gold electrodes

Cited by 17 publications

References 68 publications

Grafting of phenylboronic acid on a glassy carbon electrode and its application as a reagentless glucose sensor

Grafting of phenylboronic acid on a glassy carbon electrode and its application as a reagentless glucose sensor

Controlled Modification of Polymer Surfaces through Grafting of Calix[4]arene-Tetradiazoate Salts

Radical grafting of carbon surfaces by oxidation of 5-nitroindole derived anions

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