1999
DOI: 10.1007/bf02494552
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Electrochemical reduction of CO2 in the presence of 1,3-butadiene using a hydrogen anode in a nonaqueous medium

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Cited by 13 publications
(17 citation statements)
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“…CO 2 bubbling through a catholyte solution of 1 wt % water in DMF, saturated with butadiene, yielded up to 50% of 3-hexenedioic acid [45], a result which unfortunately was difficult to reproduce [42,46]. At that time, various substrates, like olefins, alkynes and aromatic ketones, have been electrocarboxylated in these divided cells [47].…”
Section: Reviewmentioning
confidence: 99%
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“…CO 2 bubbling through a catholyte solution of 1 wt % water in DMF, saturated with butadiene, yielded up to 50% of 3-hexenedioic acid [45], a result which unfortunately was difficult to reproduce [42,46]. At that time, various substrates, like olefins, alkynes and aromatic ketones, have been electrocarboxylated in these divided cells [47].…”
Section: Reviewmentioning
confidence: 99%
“…The direct formation of free carboxylic acids is a very interesting approach in this respect, minimizing the amount of process steps and waste ( Scheme 6 ). Protons produced at the anode, however, can have a detrimental effect on the electrocarboxylation efficiency, through cathodic formation of hydrogen, formic acid and other side products [ 41 42 ]. Hydrogen formation can be limited by usage of cathode materials with high hydrogen overvoltage like lead and mercury, or more environmentally friendly tantalum and zinc [ 43 ].…”
Section: Reviewmentioning
confidence: 99%
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“…[10,11] Protons favor the cathodic formation of hydrogen, formic acid, monocarboxylic acids and dimerization products. [10,11] Protons favor the cathodic formation of hydrogen, formic acid, monocarboxylic acids and dimerization products.…”
mentioning
confidence: 99%
“…The anodic generation of protons from water, hydrogen or ammonia, aiming at a direct formation of carboxylic acids, gives rather low current efficiencies, even when the proton supply to the cathode is controlled by a cation exchange membrane (CEM) (Scheme 1 b). [10,11] Protons favor the cathodic formation of hydrogen, formic acid, monocarboxylic acids and dimerization products.…”
mentioning
confidence: 99%