Electrochemical reduction of CO2 mediated by poly-M-aminophthalocyanines (M=Co, Ni, Fe): poly-Co-tetraaminophthalocyanine, a selective catalyst

Photo- and Electro-Catalysis

“…For example, Isaacs et al reported that CO 2 electroreduction on a glassy carbon electrode (GCE) modified with polymeric ligands with different metal centers produced different products. 72,73 When Co was the metal center, HCOOH was the only product; when Fe was the metal center, a mixture of HCHO and H 2 was produced; and when Ni was the metal center, a mixture of HCHO and HCOOH was observed.…”

Electrochemical Properties of a Conducting Film Derived from Iron(II) Tris(diaminopolypyridyl) Complex in the S(IV) Oxoanions Reduction

“…Electrochemical experiments were performed in a three compartment pyrex glass cell. UVvis spectroelectrochemical experiments were performed in a one-compartment quartz cuvette containing similar, but smaller, auxiliary and reference electrodes [17]. For UV-vis spectroscopy a Shimadzu Multispec 1501 Photodiode array spectrophotometer was used.…”

Electrochemical Reduction of S(IV) Compounds in Water‐Ethanol Solutions at Nafion/Tetraruthenated Porphyrins Glassy Carbon Modified Electrodes

“…Then it is possible to attribute the changes observed in Figure 6 to the Co center. Where this metal center should be involved in the formation of an intermediary complex or adduct [38,39]. At this stage it is possible to summarize that two factors are affecting the kinetics that controls the electroreduction of SO 2 at GC/Nf/CoTRP modified electrode: i) The slow charge propagation in the film (E), where the main evidence it is demonstrated by the effect of the concentration of SO 2 in the RDE experiments.…”