Electrochemical study of iron(II) and iron(III) compound mixtures in the solid state. Application to magnetite characterization

Electrochemical Characterization of Carbon and Weathering Steels Corrosion Products to Determine the Protective Ability Using Carbon Paste Electrode (CPE)

“…In the 1990 Scholz developed the novel electroanalytical technique i.e voltammetry of immobilised microparticles (VMP) by using paraffin impregnated graphite electrode (PIGE). Voltammetry of solid materials makes it possible to investigate the qualitative and quantitative aspects of a sample following a simple procedure while avoiding awkward chemical treatments of the sample 13, 14. The important advantages of the CPE are low ohmic resistance towards electrode and solid materials, possessing reproducible and renewable surface in aqueous solutions.…”

Electrochemical study of copper and iron compounds in the solid state by using voltammetry of immobilized microparticles: application to copper ferrite characterization

“…By comparing these results with those obtained using a composite electrode of carbon paste with an electrolytic binder [53,54], it can be concluded that voltammetry of immobilized microparticles furnishes only voltammograms due to the solid compound initially incorporated into the electrode or electrochemically generated during the electrochemical process. Table 1 The peak potential values in copper ferrites …”

“…2-12 with those that were obtained using cyclic voltammetry and a carbon paste electrode with electrolytic binder [53,54] the following can be observed: 1. The number of peaks that appeared with CPEE, for all the compounds studied and their binary mixtures, was greater than that obtained using VMP, due to solid and soluble species being retained into the carbon paste.…”

“…On the other hand, by using composite electrodes of carbon paste (CPEE), we have studied different copper and iron oxides as well as a copper ferrite CuFe 2 O 4 [53,54].…”

Electrochemistry and surface-enhanced Raman spectroscopy of CTAB modulated interactions of magnetic nanoparticles with biomolecules

“…18 The study of electrochemical behavior like redox reaction of metals at the electrode surface is also well investigated. 19 On similar lines, the electrochemistry of magnetite in bulk had been established, [20][21][22] however, very few works have investigated it in its nanoscale form. 23,24 Raman spectroscopy is a very sensitive and reliable technique to monitor the structural and chemical changes in a molecule.…”