Electrochemical study of ketones as organic phases for the establishment of micro-liquid/liquid interfaces

Zhang, Xianhao; Zhang, Shudong; Zhang, Xin; Li, Mingzhi; Gu, Yaxiong; Shao, Yuanhua

doi:10.1016/j.jelechem.2016.06.021

Journal of Electroanalytical Chemistry

2016

DOI: 10.1016/j.jelechem.2016.06.021

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Electrochemical study of ketones as organic phases for the establishment of micro-liquid/liquid interfaces

Xianhao Zhang

Shudong Zhang

Xin Zhang

et al.

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Cited by 4 publications

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“…Of course, the utilization of halogenated solvents on a large scale is very problematic from an environmental and health and safety point of view. However, for practical systems, toxic DCE could be replaced by less toxic trifluorotoluene, 48 nitriles 9 or a series of recently proposed ketone 49,50 solvents suitable for electrochemistry at liquidliquid interfaces.…”

mentioning

confidence: 99%

Mediated water electrolysis in biphasic systems

Scanlon

Peljo

Rivier

et al. 2017

Phys. Chem. Chem. Phys.

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confidence: 99%

Mediated water electrolysis in biphasic systems

Scanlon

Peljo

Rivier

et al. 2017

Phys. Chem. Chem. Phys.

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Electrochemical Study of Ion Transfers Processes at the Interfaces between Water and Trifluorotoluene and Its Derivatives

et al. 2022

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As one phase constituting of a liquid/liquid (L/L) interface, suitable organic solvents are of great significance for the study of electrochemistry at a L/L interface. In this work, the thermodynamic and kinetic parameters of simple ion transfer (IT) at the water/trifluorotoluene (W/TFT) interface were measured using micro-and nanopipettes voltammetry, respectively. In addition to the study of model ions, we have also explored some ions whose transfer potentials are close to the two ends of the potential window. Inspired by the work of the W/TFT interface, we also further developed two novel L/L interfaces and investigated various simple IT reactions based on the W/oand p-methylbenzotrifluoride (W/o-and p-MBTF) interfaces. The transfer potential and Gibbs energy of ITs across the W/o-and p-MBTF interface were determined by the analysis of the electrochemical voltametric curves. Special attention should be paid to that we can observe the IT peak or steady-state of tetraamyl ammonium (TAA + ) at W/o-and p-MBTF interfaces with no difficulty, which is rather challenging at other L/L interfaces. Compared to the classical W/1,2-dichloroethane (DCE) and W/ nitrobenzene (NB) interfaces, the W/TFT and its derivatives interfaces exhibit low toxicity, favourable stability, and wider potential windows, which can be better choices for replacing the traditional organic solvents in the electrochemical study at a L/L interface.

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Effect of the alkyl chain length of α,ω-dichloroalkane on the Gibbs energy of transfer for functional groups

Uematsu,

Tanaka,

Tanaka

et al. 2024

ANAL. SCI.

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Electrochemical study of ketones as organic phases for the establishment of micro-liquid/liquid interfaces

Cited by 4 publications

References 38 publications

Mediated water electrolysis in biphasic systems

Mediated water electrolysis in biphasic systems

Electrochemical Study of Ion Transfers Processes at the Interfaces between Water and Trifluorotoluene and Its Derivatives

Effect of the alkyl chain length of α,ω-dichloroalkane on the Gibbs energy of transfer for functional groups

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