Electrochemical switching of monomer—associate in the system tetraviologen calix[4]resorcinol—3,7-di(l-menthyl)-1,5-di(p-sulfonatophenyl)-1,5-diaza-3,7-diphosphacyclooctane

Nasybullina, G. R.; Yanilkin, V. V.; Ziganshinа, Albina Y.; Морозов, В. И.; Sultanova, Elza D.; Korshin, Dmitry E.; Spiridonova, Yu. S.; Balueva, A. S.; Карасик, А. А.; Коновалов, А. И.

doi:10.1007/s11172-013-0315-7

Cited by 5 publications

(1 citation statement)

References 30 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[33][34][35] The reversible reduction of the viologen groups to a radical cation or neutral form results in the weakening of host-guest complexes and to the appearance of new noncovalent interactions: intermolecular p dimerization of the viologen radical cations and the intermolecular hydrophobic interaction of resorcinarene platforms. [36,37] The bonding of MVCA 8 + in the nanoscale polymer matrix could open some opportunities for synthesizing new polyelectrolyte nanoparticles. A special feature of these nanoparticles is the electroswitchable change of the surface charge from a polycationic to a poly(cation radical) and neutral one, which leads to a considerable change in the In this study, the synthesis of new thermoactive polymer nanoparticles with a hollow and porous structure is reported.…”

Section: Introductionmentioning

confidence: 99%

Thermoresponsive Polymer Nanoparticles Based on Viologen Cavitands

et al. 2014

View full text Add to dashboard Cite

In this study, the synthesis of new thermoactive polymer nanoparticles with a hollow and porous structure is reported. The nanoparticles consist of viologen cavitands linked with styrene bridges. The sizes of the nanoparticles and their pores are sensitive to temperature change. The temperature increase results in the swelling of the nanoparticles and in an increase in the permeability of the nanoparticle shell. The nanoparticles are characterized by the data of NMR, IR, and UV spectroscopies, and dynamic and static light scattering (DLS, SLS). The electrochemical behavior of the nanoparticles was investigated with cyclic voltammetry. The nanoparticles can be applied to the temperature‐controlled binding and release of substrates as shown by the fluorescent dye rhodamine B. The nanoparticles encapsulate and release rhodamine B in response to the change in temperature from 25 to 40 °C.

show abstract

Section: Introductionmentioning

confidence: 99%

Thermoresponsive Polymer Nanoparticles Based on Viologen Cavitands

et al. 2014

View full text Add to dashboard Cite

show abstract

Electrochemically controlled binding of bis-P,P-chelate platinum(II) dication to 3,7-di(2-pyridyl)-1,5-diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex and ferrocyanide ion with tetraviologen calix[4]resorcinol

et al. 2015

View full text Add to dashboard Cite

Mediated electrochemical synthesis of metal nanoparticles

Yanilkin¹,

Nasretdinova²,

Kokorekin³

2018

Russ. Chem. Rev.

View full text Add to dashboard Cite

The review integrates and analyzes data of original studies on the mediated electrosynthesis of metal nanoparticles — a new efficient and environmentally attractive process for obtaining these particles in the solution bulk. The general principles and specific features of electrosynthesis of metal nanoparticles by mediated electroreduction of metal ions and complexes are considered. The discussed issues include the role of cyclic voltammetry in the development of this method, the method efficiency, some aspects of selection of mediators, and aggregation, stabilization and catalytic activity of the metal nanoparticles thus obtained. Analysis of the results of mediated electrosynthesis of Pd, Ag, PdAg, Au, Pt and Cu nanoparticles stabilized by various compounds and mediated electrogeneration of highly active metal particles is used as basic data for discussion. The bibliography includes 247 references.

show abstract

Electrochemical switching of monomer—associate in the system tetraviologen calix[4]resorcinol—3,7-di(l-menthyl)-1,5-di(p-sulfonatophenyl)-1,5-diaza-3,7-diphosphacyclooctane

Cited by 5 publications

References 30 publications

Thermoresponsive Polymer Nanoparticles Based on Viologen Cavitands

Thermoresponsive Polymer Nanoparticles Based on Viologen Cavitands

Electrochemically controlled binding of bis-P,P-chelate platinum(II) dication to 3,7-di(2-pyridyl)-1,5-diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex and ferrocyanide ion with tetraviologen calix[4]resorcinol

Mediated electrochemical synthesis of metal nanoparticles

Contact Info

Product

Resources

About