Electrochemical Synthesis of Gold‐N‐Heterocyclic Carbene Complexes**

Abstract

An electrochemical synthesis of gold(I)‐N‐heterocyclic carbene (Au‐NHC) complexes has been developed. The electrochemical methodology uses only imidazolium salts, gold metal electrodes, and electricity to produce these complexes and the only by‐product is hydrogen gas. This high‐yielding and operationally simple procedure has been used to produce seven mononuclear and three dinuclear Au‐NHC complexes. The electrochemical procedure facilitates a clean reaction with no by‐products. As such, Au‐NHC complexes can be directly transferred to catalytic reactions without work‐up or purification. The Au‐NHC complexes were produced on‐demand and tested as catalysts in a vinylcyclopropanation reaction. All mononuclear Au‐NHC complexes performed similarly to or better than the isolated complexes, showcasing how the electrochemical procedure can speed up catalyst screening and reaction development.