2021
DOI: 10.1021/acs.nanolett.1c00778
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Electrochemically Induced Strain Evolution in Pt–Ni Alloy Nanoparticles Observed by Bragg Coherent Diffraction Imaging

Abstract: Strain is known to enhance the activity of the oxygen reduction reaction in catalytic platinum alloy nanoparticles, whose inactivity is the primary impediment to efficient fuel cells and metal−air batteries. Bragg coherent diffraction imaging (BCDI) was employed to reveal the strain evolution during the voltammetric cycling in Pt−Ni alloy nanoparticles composed of

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Cited by 21 publications
(23 citation statements)
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“…Indeed, it is largely accepted that fundamental reactivity descriptors ( e.g. surface strain, chemistry, and/or crystallinity) of Pt-based electrocatalysts measured and tailored ex situ are not necessarily conserved in situ due to surface reconstruction in the particular environment of the PEMFC cathode on operation. , Indeed, to the best of our knowledge, such in situ and/or operando techniques have never been used to investigate this promising novel class of Pt-REM/C nanoalloys.…”
Section: Introductionmentioning
confidence: 99%
“…Indeed, it is largely accepted that fundamental reactivity descriptors ( e.g. surface strain, chemistry, and/or crystallinity) of Pt-based electrocatalysts measured and tailored ex situ are not necessarily conserved in situ due to surface reconstruction in the particular environment of the PEMFC cathode on operation. , Indeed, to the best of our knowledge, such in situ and/or operando techniques have never been used to investigate this promising novel class of Pt-REM/C nanoalloys.…”
Section: Introductionmentioning
confidence: 99%
“…Bragg coherent X-ray diffraction imaging (BCDI) allows three-dimensional (3D) nanoscale strain measurements, with a typical spatial resolution of a few tens of nanometres and a strain resolution on the order of ∼2×10 −4 (Hofmann et al, 2017b). BCDI has been applied to study crystal defects and lattice strain in a variety of materials, including noble metals (Robinson et al, 2001), alloys (Kawaguchi et al, 2021), geological compounds (Yuan et al, 2019), semiconductors (Lazarev et al, 2018), and functional materials (Dzhigaev et al, 2021). An advantage of using BCDI is the ability to study 3D volumes up to 1 µm in size at ambient conditions.…”
Section: Introductionmentioning
confidence: 99%
“…10 This is part of the motivation for recently investing in modern nanofocus instruments at most of the world's synchrotrons, [11][12][13][14][15] enabling operando experiments with a variety of nanobeam techniques. [16][17][18][19][20][21] In particular, BCDI has been increasingly applied to problems in heterogeneous catalysis, 22 electrocatalysis, [23][24][25] and complex electrochemical energy conversion systems. [26][27][28][29] The BCDI method requires extremely high flux densities when applied to small and industrially relevant nanoparticles, 30 and the recently constructed 4:th generation synchrotron sources are expected to enable this by providing brighter and higher-quality X-ray beams.…”
Section: Introductionmentioning
confidence: 99%