Electrochemistry of Rhodium (III) in Trihexil(tetradecyl) Phosphonium Bis(2,4,4-trimethylpentyl) Phosphinate Ionic Liquid (Cyphos IL 104<sup>®</sup>) and Its Deposition

Electrochemistry is an important research domain to realize the electrochemical transitions of a target species in its feed solution. The area has wide applications in both non-aqueous and aqueous reprocessing of spent nuclear fuels. Here, all of the literature reports dealing with the electrochemical behavior of lanthanides and actinides in ionic liquid (IL) solvents containing strongly coordinating extractants and the feasibility of their direct electrodeposition intended towards a novel wing of the aqueous reprocessing are gathered and discussed in a comprehensive manner. The variation in the electrochemical results in IL phase based on the ligand structure and the functional moiety present in it has been highlighted by correlating the complexing ability of these extractants with metal ions. Decisive parameters such as diffusion coefficient (D), charger transfer coefficient (), charge transfer rate constant (ks), activation energy (Ea), etc., were compared with each other to draw out the consequence of a particular ligand/IL system. The novelty of electrochemistry in neutral ligand ionic liquids has been showcased in detail. The practicality of direct electrodeposition from the extracted IL phase has also been covered in the review to draw an innovative pathway of metal ion recovery.

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Progress on Electrodeposition of Metals and Alloys Using Ionic Liquids as Electrolytes

Costa

Neto

2022

Metals

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The electrodeposition process of metals and their alloys is widely used in the automotive, space, electronics, computing, jewelry, and other consumer items industries. Over the years, the search for new coatings with more suitable characteristics for their application led to the use of ionic liquids (ILs) as electrolytic solutions. In addition to having good conductive properties, the growing interest in these solvents has environmental appeal due to their low toxicity. Furthermore, the ability of these electrolytes to dissolve compounds containing less soluble metals makes them potential substitutes for environmentally harmful solvents. In this sense, this review describes the current state and the innovations concerning the electrodeposition of metals and alloys using ILs as electrolytes in the last five years. Metals were classified into five groups (common, light, noble, rare earth, and others), highlighting not only the ability to form a smooth, homogeneous, and anti-corrosive deposit, but also the reactive capacity of metals in hydrogen evolution and catalytic processes.

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Electrochemistry of Rhodium (III) in Trihexil(tetradecyl) Phosphonium Bis(2,4,4-trimethylpentyl) Phosphinate Ionic Liquid (Cyphos IL 104^®) and Its Deposition

Cited by 3 publications

References 20 publications

Trihexyl(tetradecyl)phosphonium bis-2,4,4-(trimethylpentyl)phosphinate micellar behavior in the extraction of Ag(I) from acidic nitrate media

Trihexyl(tetradecyl)phosphonium bis-2,4,4-(trimethylpentyl)phosphinate micellar behavior in the extraction of Ag(I) from acidic nitrate media

Electroanalytical Chemistry of Lanthanides/Actinides and the Feasibility of Direct Electrodeposition in Ligand Containing Ionic Liquids: A Comprehensive Review

Progress on Electrodeposition of Metals and Alloys Using Ionic Liquids as Electrolytes

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Electrochemistry of Rhodium (III) in Trihexil(tetradecyl) Phosphonium Bis(2,4,4-trimethylpentyl) Phosphinate Ionic Liquid (Cyphos IL 104®) and Its Deposition

Cited by 3 publications

References 20 publications

Trihexyl(tetradecyl)phosphonium bis-2,4,4-(trimethylpentyl)phosphinate micellar behavior in the extraction of Ag(I) from acidic nitrate media

Trihexyl(tetradecyl)phosphonium bis-2,4,4-(trimethylpentyl)phosphinate micellar behavior in the extraction of Ag(I) from acidic nitrate media

Electroanalytical Chemistry of Lanthanides/Actinides and the Feasibility of Direct Electrodeposition in Ligand Containing Ionic Liquids: A Comprehensive Review

Progress on Electrodeposition of Metals and Alloys Using Ionic Liquids as Electrolytes

Contact Info

Product

Resources

About

Electrochemistry of Rhodium (III) in Trihexil(tetradecyl) Phosphonium Bis(2,4,4-trimethylpentyl) Phosphinate Ionic Liquid (Cyphos IL 104^®) and Its Deposition