Electrodeposition of fluorine-doped lead dioxide

Величенко, А. Б.; Devilliers, Didier

doi:10.1016/j.jfluchem.2006.11.010

Cited by 126 publications

(52 citation statements)

References 36 publications

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“…The introduction of F − into the Ti/PbO 2 electrode results in a notable rise for the potential of the organics degradation. The research on F − doping into the Ti/ PbO 2 electrode (Ti/F-PbO 2 ) mainly focused on preparation methods, physical and chemical properties, and mechanism of the electrochemical processes [21,22].…”

Section: Introductionmentioning

confidence: 99%

Comparison of electrocatalytic characterization of Ti/Sb-SnO2 and Ti/F-PbO2 electrodes

Yao

Jiao

et al. 2015

J Solid State Electrochem

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Electrocatalytic oxidation is a promising process for degrading toxic and biorefractory organic pollutants in wastewater treatment. Selection of electrode materials is crucial for electrochemical oxidation process. In this study, Ti/F-PbO 2 and Ti/Sb-SnO 2 electrodes were chosen to compare their electrocatalytic characterization, which were prepared by electrodeposition and thermal decomposition method, respectively. The surface morphology and crystal structure of two electrodes were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The linear polarization curves show that Ti/Sb-SnO 2 electrodes possess higher oxygen evolution overpotential than Ti/F-PbO 2 electrodes. But the stability and corrosion resistance ability of Ti/F-PbO 2 electrode was higher than that of Ti/Sb-SnO 2 electrode. The electrocatalytic activity of Ti/F-PbO 2 and Ti/Sb-SnO 2 electrodes was examined for the electrochemical oxidation of malachite green (MG). The bulk electrolysis shows that the Ti/SbSnO 2 electrodes exhibit the higher electrocatalytic activity for the degradation of MG than Ti/F-PbO 2 electrodes, and the degradation process is good fitting for the pseudo-first order reaction. The higher electrocatalytic activity of Ti/ Sb-SnO 2 electrodes can be attributed to the higher oxygen evolution overpotential.

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Section: Introductionmentioning

confidence: 99%

Comparison of electrocatalytic characterization of Ti/Sb-SnO2 and Ti/F-PbO2 electrodes

Yao

Jiao

et al. 2015

J Solid State Electrochem

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“…2 and width measurements presented in Table 1 0%: 0. [12], fluoride [12][13][14] and nickel(II) [4], and novel additives tin(II) oxide, EDTA, gadolinium(III) oxide, and zinc(II) oxide were compared. PVP was also studied due to its use in controlling the particle size of PbO 2 coatings [15].…”

Section: + /Pbo 2 Couplementioning

confidence: 99%

The separator-divided soluble lead flow battery

et al. 2018

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The soluble lead flow battery (SLFB) is conventionally configured with an undivided cell chamber. This is possible, unlike other flow batteries, because both electrode active materials are electroplated as solids from a common species, Pb 2+ , on the electrode surfaces during charging. Physically separating the active materials has the advantage that a single electrolyte and pump circuit can be used; however, failure mechanisms such as electrical shorting may be observed. In addition, a common electrolyte requires that any electrolyte additives are compatible with both half-cell reactions. This paper introduces two new configurations; semi-and fully divided for the SLFB. Cationic, anionic, and microporous separators are assessed for ionic conductivity in SLFB electrolytes, showing that their incorporation adds as little as a 20 mV to the cell voltage. Voltammetry shows the effect of additives on the equilibrium potential and stripping overpotential of PbO 2 . It is then demonstrated that the incorporation of a separator into the SLFB can reduce failure due to electrical shorting and permit electrode-specific additives to be used. A unit flow cell with electrode area of 100 cm 2 is shown to operate for over 300 Ah in the semi-divided configuration, more than doubling the previously reported cycle life for cells of similar size. Graphical AbstractKeywords Soluble lead · Methanesulfonic acid · Flow battery · SLFB

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“…Up to our knowledge, no results describing PbO 2 deposition at gold electrode covered by Nafion® layer exist in the literature. There were, however, a couple of papers dealing with PbO 2 electrodeposition from the solutions of Pb(II) ion in the presence of dissolved Nafion® [32,33]. The results of these investigations were very interesting and showed that the presence of Nafion® did not hinder the electrodeposition process but rather facilitated it.…”

Section: Introductionmentioning

confidence: 99%

Anodic deposition of lead dioxide at Nafion® covered gold electrode

Burazer

Sopčić

Mandić

2016

J Solid State Electrochem

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Anodic electrodeposition of lead dioxide at the bare and Nafion® covered gold electrode was studied by cyclic voltammetry and chronoamperometry. The results showed that Nafion® layer has a favourable effect on the efficiency of the deposition process which was caused by both thermodynamic and kinetic reasons. Electrodeposition process at Nafion® covered gold electrode goes via Pb(III) intermediate species which are stabilized within Nafion® membrane. The final PbO 2 deposit crystallizes in tetragonal β-PbO 2 form.

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Electrodeposition of fluorine-doped lead dioxide

Cited by 126 publications

References 36 publications

Comparison of electrocatalytic characterization of Ti/Sb-SnO2 and Ti/F-PbO2 electrodes

Comparison of electrocatalytic characterization of Ti/Sb-SnO2 and Ti/F-PbO2 electrodes

The separator-divided soluble lead flow battery

Anodic deposition of lead dioxide at Nafion® covered gold electrode

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