Electrodeposition of iron–molybdenum–tungsten coatings from citrate electrolytes

Karakurkchi, Ann; Ved, Maryna; Сахненко, Н. Д.; Yermolenko, Iryna

doi:10.1134/s1070427215011018x

Cited by 17 publications

(11 citation statements)

References 7 publications

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“…Composition of the electrolyte was selected based on the results of preliminary studies into the influence of component concentration of the solution on the composition, morphology of the surface and current efficiency of the electrolytic Fe-Co-Mo alloys [32]. Nevertheless, control of the quality of coatings and over effectiveness of the electrolysis, extending of range of the content of the alloy-forming components relates to the plane of using the non-stationary current.…”

Section: Results Of the Formation Of A Ternary Fe-co-mo Alloymentioning

confidence: 99%

Research into influence of the electrolysis modes on the composition of galvanic Fe-Co-Mo coatings

Yermolenko

Ved

Karakurkchi

et al. 2017

EEJET

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Section: Results Of the Formation Of A Ternary Fe-co-mo Alloymentioning

confidence: 99%

Research into influence of the electrolysis modes on the composition of galvanic Fe-Co-Mo coatings

Yermolenko

Ved

Karakurkchi

et al. 2017

EEJET

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“…В работах [18][19][20][21] представлены результаты собствен ных исследований по формированию покрытий железа с молибденом и вольфрамом на подложках из меди и низкоуглеродистой стали из цитратных электролитов железа(ІІІ). Электролиты этого типа были выбраны для формирования многокомпонентных покрытий железа с молибденом и вольфрамом на серых чугунах СЧ18.…”

Section: исследование существующих решений проблемыunclassified

“…%, чем наблюдалось при формировании покрытий на подложках из низко-легированной стали [19,20]. Также отличается и ход зависимостей содержания тугоплавких компонентов в покрытии от плотности тока.…”

Section: методы исследованийunclassified

A study of formation peculiarities and properties of iron coatings with refractory metals on gray cast iron SCH18

Каракуркчи

2017

TAPR

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“…Obviously, in each individual case, the formation of the coating depends on the qualitative and quantitative composition of the electrolyte and on the synthesis conditions, wherein the modes and parameters of the electrolysis will determine in a particular way the concentration ratio of the alloy components and phase composition of the coatings [9]. …”

Section: Introductionmentioning

confidence: 99%

Composition, Morphology, and Topography of Galvanic Coatings Fe-Co-W and Fe-Co-Mo

et al. 2017

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Ternary coatings Fe-Co-W with an iron content of 40–55 at.%, cobalt 39–44 at.%, and tungsten 4–12 at.% and Fe-Co-Mo with an iron content of 40–55 at.%, cobalt 39–44 at.%, and tungsten 4–12 at.% were obtained by galvanostatic and pulse electrolysis on the mild steel substrate from iron(III) citrate-based electrolyte. The influence of electrolysis mode and parameters on composition of deposited alloys was studied. The competing reduction of iron and tungsten in Fe-Co-W coatings as well as the competitive deposition of iron and cobalt in Fe-Co-Mo coatings at various current densities were defined. Simultaneously, the alloy enrichment with molybdenum is more marked at a pulse mode. Atomic force microscope analysis of the Fe-Co-W alloy coating morphology and surface topography indicates their globular structure with spherical grains in the range of 2.5–3.5 μm. The surface of Fe-Co-Mo is characterized by parts of a globular structure with an average conglomerate size of 0.3–0.5 μm and singly located cone-shaped hills with a base diameter of 3 μm. Sites with a developed surface were detected within the same scan area which topography is identical to the crystal lattice of cobalt with the crystalline conglomerate sizes in the range of 0.2–1.75 μm.

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Electrodeposition of iron–molybdenum–tungsten coatings from citrate electrolytes

Cited by 17 publications

References 7 publications

Research into influence of the electrolysis modes on the composition of galvanic Fe-Co-Mo coatings

Research into influence of the electrolysis modes on the composition of galvanic Fe-Co-Mo coatings

A study of formation peculiarities and properties of iron coatings with refractory metals on gray cast iron SCH18

Composition, Morphology, and Topography of Galvanic Coatings Fe-Co-W and Fe-Co-Mo

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