Electrokinetic energy conversion through cylindrical microannulus with periodic heterogeneous wall potentials

Abstract

In microfluidic electrokinetic flows, heterogeneous wall potentials are often required to fulfill some functions, such as increasing dispersion and mixing efficiency. In this paper, we study the pressure-driven electrokinetic flow through microannulus with heterogeneous wall potentials in circumferential direction. The streaming potential induced by the ions accumulating in downstream of the microannulus is considered and the electrokinetic energy conversion efficiency is further investigated. Interestingly, based on the method of Fourier expansion, the analytical solutions of fluid velocity, streaming potential and energy conversion efficiency are derived for arbitrary peripheral distribution of the small wall potential for the first time. Four specific patterned modes of the heterogeneous wall potential, i.e., constant, step, sinusoid with period 2π and sinusoid with period π/2 are represented. The distributions of the electric potential and the velocity for four different modes are depicted graphically. Furthermore, the variations of the streaming potential and the electrokinetic energy conversion efficiency with related parameters are also discussed. Results show that when these integral values from -π to π associated with the wall potentials are identical, the streaming potential and the electrokinetic energy conversion efficiency corresponding to different modes are the same. Additionally, the amplitude of fluid velocity peripherally reduces with the increase of the wavenumber of wall potential distribution in θ-direction.

Energy harvesting from water streaming at charged surface

“…Thus, the region marked in blue in Figure 6 ranges from a few nm to tens of µm, with a maximum efficiency of 25% in theory by using viscoelastic fluids in a polyelectrolyte-grafted nanochannel [127]. Other minor effects were discussed for the influences of energy conversion performances, like the temperature [115,120,176], Stern layer effects [160], shape of micro/nanochannel [177][178][179], and local viscosity variations of liquids [180,181].…”