Electrolytic synthesis of chloroacetic acids in a filter-press reactor from polychloromethanes

Olloqui‐Sariego, José Luis; Molina, Víctor M.; González-Arjona, D.; Roldán, Emilio; Domí­nguez, Manuel

doi:10.1016/j.elecom.2010.04.030

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Activated C-c Double Bonds and Organic Halides1

Electrocarboxylation Of Organic Halides Compounds In Ionic L...1

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Cited by 4 publications

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“…Galvanostatic electrolysis in an undivided filter-press flow reactor consisting of a planar Zn cathode and a planar Al sacrificial anode afforded with 90% current efficiency in 0.1 M Bu 4 NClO 4 in acetonitrile 85% of TCA and 69% of DCA, respectively [50].…”

Section: Activated C-c Double Bonds and Organic Halidesmentioning

confidence: 99%

Contributions of organic electrosynthesis to green chemistry

Schäfer

2011

Comptes Rendus. Chimie

254

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Section: Activated C-c Double Bonds and Organic Halidesmentioning

confidence: 99%

Contributions of organic electrosynthesis to green chemistry

Schäfer

2011

Comptes Rendus. Chimie

254

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“…Ag [15,68,69], Hg [64], Cu [67], Ti [67], Zn [70] and steel [68,71]. Of these materials, Ag is a powerful electrocatalyst for the formation of the reactive anion which is the bottleneck step of the electrocarboxylation [15].…”

Section: Electrocarboxylation Of Organic Halides Compounds In Ionic L...mentioning

confidence: 99%

Chapter 7. Electrocarboxylation in Ionic Liquids

Zhao

Horne

Bond³

et al. 2018

Energy and Environment Series

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Four drivers have stimulated recent research into the electrochemical conversion of carbon dioxide into fuels and chemicals: (1) The prospect of using gaseous CO2, a gas previously considered a useless waste product, as an economical and abundant source of carbon. (2) The urgent need for effective energy storage technology. (3) The versatility of electrochemical methods. (4) Concern about the rising levels of CO2 in the atmosphere. Within this thriving research field, one area that has received significant attention is the electrocarboxylation of organic compounds and which provides the focus of this review. Electrocarboxylation occurs when a reactive radical anion generated electrochemically from an organic substrate (or CO2) reacts with CO2 (or an organic substrate) to form a carboxylate. However, the high reactivity of the electrogenerated reactant means many factors can influence the reaction pathway, particularly the nature of the solvent and electrode. Special attention is given in this review to the use of ionic liquids in electrocarboxylation because these neoteric solvents provide promising alternatives to organic molecular solvents. Finally, some perspectives on potential industrial application of ionic liquids in electrocarboxylation are provided.

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