use noble metallic nanomaterials. [9,10] In recent decades, many groups have brought together plasmonic nanostructures and molecular excitons to form plexcitonic coupling systems. [11] Strong coupling has been observed in many systems, such as silver platelet-J-aggregate nanocomposites, [12] gold nanostar-J-aggregate hybrid systems, [13] and gold nanoshell-J-aggregate complexes. [3] However, plasmonic nanostructures are usually associated with a high level of Joule heating losses at optical frequencies, which limit the efficiency of these coupling systems. [14][15][16] It is also believed that molecular excitons will become instable if the temperature of coupling systems rises, [17] which means that these plexcitonic coupling systems cannot work effectively for a long time. Hence, it is necessary to search for a new type of material to replace the plasmonic nanostructures in these systems.After the demonstration of magnetic dipole resonances of silicon nanospheres in the visible region, [18] all-dielectric materials that could manipulate light at subwavelength scales (similar to metallic materials) were widely studied, especially the high-refractiveindex materials (e.g., silicon, germanium, gallium phosphide, and gallium arsenide). [19][20][21] Simple metallic nanostructures, such as nanospheres or nanorods, can exhibit the electric response only. However, the magnetic response can appear in specially designed metallic nanostructures such as split-ring resonators, U-shape structures, and pairs of nanorods. [22][23][24] Unlike noble metallic materials, all-dielectric materials, even a nanosphere, can support both the electric mode and magnetic mode naturally, which is attributed to the nearly negligible imaginary part of their refractive indices. [19,21,25,26] Because of the magnetic response, a silicon nanoparticle can scatter light asymmetrically as a "Huygens" source. [27] Moreover, directional Fano resonance [28] and magnetic hotspots [29] have been achieved in silicon nanodimers. Therefore, all-dielectric materials may offer an alternative route toward addressing the problems facing plexcitonic coupling systems. Yan et al. generated scattering dark states through the Fano interference between excitons and silicon nanogrooves, [30] and Wang et al. explored resonance coupling in silicon nanosphere-J-aggregate heterostructures and observed a mode Coupling between light and matter has many infusive physical effects and potential applications. Large Rabi splitting energy is achieved in many plasmonic nanostructures; however, these noble metallic materials generally suffer from a high level of Joule heating losses at optical frequencies.As an alternative strategy, all-dielectric materials for manipulating light at the subwavelength scale have attracted enormous interest. However, the understanding of the interactions between all-dielectric nanostructures and molecular excitons remains limited to date. Here, the use of a germanium nanogroove as a new all-dielectric metasurface building block is demonstrated for the ...