Recent developments in non-planar polycyclic aromatic molecules bearing heterole units have been reviewed, including internally and externally heteroatom doped corannulenes, rim and benzylic heteroatom doped sumanenes, hexapyrrolohexaazacoronenes, and hetero[n]circulenes. CONTENTS 1. Introduction 2. Heteroatom doped corannulenes 2-1. Internally heteroatom doped corannulenes 2-2. Externally heteroatom doped corannulenes 3. Heteroatom doped sumanenes 3-1. Rim heteroatom doped sumanenes 3-2. Benzylic heteroatom doped sumanenes 4. Other heteroatom doped bowl shaped PAHs