Resistance switching effects in metal/perovskite contacts based on epitaxial c-axis oriented YBa 2 Cu 3 O 6+c (YBCO) thin films with different crystallographic orientations have been studied. Three types of Ag/YBCO junctions with the contact restricted to (i) c-axis direction, (ii) ab-plane direction, and (iii) both were designed and fabricated, and their current-voltage characteristics have been measured. The type (i) junctions exhibited conventional bipolar resistance switching behavior, whereas in other two types the low-resistance state was unsteady and their resistance quickly relaxed to the initial high-resistance state. Physical mechanism based on the oxygen diffusion scenario, explaining such behavior, is discussed.The resistive switching (RS) effect observed in capacitor-like metal/insulator/metal junctions belongs to the most promising candidates for the next generation of the memory cell technology based on a sudden change of the junction resistance caused by an electric field applied to the metal electrodes. Despite a burst of activities triggered by increasing technological interest for this phenomenon 1,2 , details of its physical mechanism are still debated. The most studied are highly insulating binary transition metal oxides, where a key ingredient of the RS effect is believed to be a redistribution of oxygen ion vacancies which results in the formation (low-resistive state -LRS) and rupture (high-resistive state -HRS) of conductive filaments within the insulating media. 1,2 For more complex oxides like perovskites, the process of the RS effect seems to be more complicated. In this case the switching was usually bipolar whereas in simple binary oxides bi-and unipolar behavior has been observed. [3][4][5] In the following we are studying the RS effect in contacts based on conducting YBa 2 Cu 3 O 6+c (YBCO) films, compounds with a crystal structure which promotes electronic transport primarily within a twodimensional layer of atoms. One of the ways to shed light on their basic properties is to study an electricfield effect in the normal state. Up to now, two mutually exclusive field-effect mechanisms have been proposed. The first one, fundamentally electronic, is based on a conventional approach which takes into account the Coulomb interaction of an applied electric field with mobile current carriers. 6 It is fast, symmetric with respect to the bias polarity and results in the enhancement or depletion of the number of charge carriers within a few near-surface atomic layers. 6 The second mechanism 7 is related to direct interaction of oxygen ions with an applied electric field which causes significant charge carrier rearrangement due to a comparatively small oxygen migration energy and high density of vacancies in the oxygen sub-lattice in an optimal doping state. Such a process is characterized by a slower time constant and can be unequal in magnitude at positive and negative voltage biases of identical absolute value. 7 To choose between the two mechanisms of field-induced changes in normal-state...