2023
DOI: 10.1002/cphc.202300064
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Electron and Spin Delocalization in [Co6Se8(PEt3)6]0/+1 Superatoms

Yunyao Xu,
Jia Chen,
Alexander P. Aydt
et al.

Abstract: Molecular clusters can function as nanoscale atoms/superatoms, assembling into superatomic solids, a new class of solid‐state materials with designable properties through modifications on superatoms. To explore possibilities on diversifying building blocks, here we thoroughly studied one representative superatom, Co6Se8(PEt3)6. We probed its structural, electronic, and magnetic properties and revealed its detailed electronic structure as valence electrons delocalize over inorganic [Co6Se8] core while ligands f… Show more

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