The results of new studies of creating protective oxide coatings based on Al 2 O 3 (Si, Mn) and deposited onto aluminum alloys using electrolyte-plasma oxidation are presented. An analysis is performed by scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), X ray diffraction, Rutherford backscattering of 4 He + and protons, nanoindentation, scratching, friction coefficient measure ments, and acoustic emission measurements. The results demonstrate that the deposited coatings have a high quality, hardness, and wear resistance and a low thermal diffusivity. Apart from Al 2 O 3 , the coatings are found to have Si, Mn, C, and Ca. The stoichiometry of the coatings is determined. The density and hardness of the coatings are close to those of α Al 2 O 3 in the coating on an Al-Cu (D 16) substrate, and these values of the coating on an Al-Mg (S006) are lower by a factor of 1.5.