Absolute cross sections for electron impact ionization of multiply charged
argon ions (Arq+) have been measured in an animated crossed electron–ion
beam experiment. Results are reported for single ionization (SI) (q = 4–6,
8, 10 and 11) ions and for double ionization (DI) (q = 5–11).
The measurements cover the energy range from threshold to
about 6000 eV. The direct process is seen to dominate SI for q = 8, 10
and 11. For charge states 4–6, excitation–autoionization processes are seen to
largely contribute to the ionization signal. In addition, metastable states are
unambiguously identified for Ar5+ and Ar6 +. Ionization–autoionization
(IA) from the L shell accounts predominantly for DI of Arq+ (q = 5, 6).
For charge states 7–11 direct DI is found to decrease strongly with respect to IA
from the K shell.