The mechanisms leading to the production of hollow K shell atoms via single photon impact were investigated for a variety of light elements with 12 ≤ Z ≤ 23. The double 1s vacancy states were produced by irradiating the samples with intense monoenergetic synchrotron radiation beams. The double-to-single K-shell photoionization probabilities P KK and the absolute double K-shell photoionization cross sections 2+ were determined by measuring with a high-resolution bent von Hamos crystal spectrometer the K˛h hypersatellite X-ray emission of the samples. The measurements were performed over a wide range of incoming photon energies from threshold up to energies beyond the broad maximum of the double-tosingle photoionization cross section ratios. The P KK and 2+ were determined from the relative yields of the resolved K˛h hypersatellite lines. For Mg, Al and Si, the two-electron one-photon (TEOP) K˛˛h transitions which represent an alternative but much weaker decay channel for double 1s vacancy states could be also observed, using a highly efficient flat crystal wavelength dispersive spectrometer. This observation of single photon-induced TEOP transitions has shown that the I(K˛h)/I(K˛˛h) branching ratios are very poorly reproduced by most of existing theoretical models. Besides the relative yields of the hypersatellite and TEOP transitions, the energies and natural linewidths of the K˛h and K˛˛h X-ray lines were also determined. The energies are found to be in good agreement with different theoretical predictions, whereas the linewidths are significantly underestimated by the calculations, except if non-lifetime broadening effects such as the outer-shell ionization and the open valence configuration are taken into consideration.