Abstract.Recently developed collisional electron spectroscopy (CES) method, based on identification of gas impurities by registration of groups of nonlocal fast electrons released by Penning ionization of the impurity particles by helium metastable atoms, is verified experimentally. Detection and identification of atoms and molecules of gas impurities in helium at pressures of 14 -90 Torr with small admixtures of Ar, Kr, CO2, and N2 are carried out. The nonlocal negative glow plasma of short dc microdischarge is used as most suitable medium. Records of the energy spectra of penning electrons are performed by means of an additional electrode -sensor, located at the boundary of the discharge volume. Maxima appear in the electron energy spectra at the characteristic energies corresponding to Penning ionization of the impurity particles by helium metastable atoms.
IntroductionThe plasma electron spectroscopy (PLES) method, developed by Kolokolov at al.[1] represents a new approach for studies of elementary plasma processes and atomic constants. On the base of the PLES method a new method for identification of gas impurities is proposed by Kudryavtsev [2]. It is based on identification of gas impurities by registration of groups of nonlocal fast electrons, released in reaction of Penning ionization of the impurity particles by helium metastable atoms. Further development of PLES method for identification of unknown species in a gas phase is reported in [3]. In [1-3] the nonlocal afterglow plasma of positive column at low pressures (0.5 -3.5 Torr) is used, and temporal resolution of the registration system is applied, which complicates the devices.In this paper the new method of collisional electron spectroscopy (CES), whose basic principles are patented by Kudryavtsev at al. [4] is experimentally veryfied. The CES method is based on measurements of energy spectra R( ) of fast electrons released in Penning ionization of the impurities atoms or molecules by metastable atoms of the main gas: