Electron paramagnetic resonance of Gd3+ in ThBr4 single crystals at room temperature

Hubert, S.; Eméry, J.; Edelstein, Norman M.; Fayet, J. C.

doi:10.1016/0038-1098(85)90766-5

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Ground-state Splitting Of F 7 Ions1

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2010

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Cited by 11 publications

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“…The lanthanides in such a configuration are Eu 2+ , Gd 3+ , and Tb 4+ ; and the actinide ions include Am 2+ , Cm 3+ , and Bk 4+ . Early arguments were focused on the Gd 3+ ion since that the ground-state crystal-field splitting observed in EPR experiments was less than 0.5 cm À1 [63] and could not be interpreted satisfactorily by the crystal-field theory. A series of mechanisms were considered but failed to provide a consistent interpretation [62,64,65].…”

Section: Ground-state Splitting Of F 7 Ionsmentioning

confidence: 99%