Electron paramagnetic resonance of Nd3+ in YK(MoO4)2

Livanova, L. D.

doi:10.1007/bf00739244

J Struct Chem

1967

DOI: 10.1007/bf00739244

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Electron paramagnetic resonance of Nd3+ in YK(MoO4)2

L. D. Livanova

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1969

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Optical, EPR, and ENDOR Studies of CdF2:V3+, V2+

Borcherts

Lohr

1969

The Journal of Chemical Physics

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Single crystals of CdF2 containing either V3+ or V2+ ions have been prepared and studied by optical, EPR, and ENDOR techniques. As expected, the properties of V3+ in the eight-coordinated (cubal) environment closely resemble those of Ni2+ in octahedral sites. The ENDOR data show that Ms = ± 1, confirming the identification of the ion as V3+. The V2+ ions, produced by heating samples containing V3+ in Cd vapor, exhibit evidence for a large trigonal Jahn–Teller distortion of the cubal site. On the basis of the EPR and optical data it is suggested that the environment about the V2+ ions may be more nearly octahedral than cubal, thus reflecting the presence of a static trigonal field comparable in magnitude to the (undistorted) cubic field. Some optical and EPR data are presented for isoelectronic Cr3+ ions, which also display a strong Jahn–Teller effect.

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Optical, EPR, and ENDOR Studies of CdF2:V3+, V2+

Borcherts

Lohr

1969

The Journal of Chemical Physics

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Electron paramagnetic resonance of Nd3+ in YK(MoO4)2

Cited by 1 publication

References 5 publications

Optical, EPR, and ENDOR Studies of CdF2:V3+, V2+

Optical, EPR, and ENDOR Studies of CdF2:V3+, V2+

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