Electron Spectra of Oxide Films on Pure Iron and an Iron-Aluminium Alloy

Hoar, T. P.; Talerman, M.; Sherwood, Peter M. A.

doi:10.1038/physci240116b0

Cited by 13 publications

(3 citation statements)

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“…From the binding energy observed for Fe3P~/~ (56.4 eV relative to metallic iron at 53.1 eV) in Fig. 8 it appears that the dominant oxidation products on the surface are Fe203 (24,25), although there is also the possibility that FeaO4 is present (23). The spectra in Fig.…”

Section: Typicalmentioning

confidence: 88%

Oxidation Studies of Permalloy Films by Quartz Crystal Microbalance, AES, and XPS

Lee

Eldridge

1977

J. Electrochem. Soc.

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Section: Typicalmentioning

confidence: 88%

Oxidation Studies of Permalloy Films by Quartz Crystal Microbalance, AES, and XPS

Lee

Eldridge

1977

J. Electrochem. Soc.

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“…(57,58,61,(64)(65)(66)(67)(68)(69)(70)(71)(72) Hoar et at. (57) found that the air-formed oxide film on an iron-1.56 wt.% aluminum alloy is largely Fe 3 0 4 . Chen et at.…”

Section: Studies Of Iron Alloysmentioning

confidence: 98%

“…(17. 57-63) Hoar et al (57) used surface charging differences to distinguish between Fe 2 0 3 and Fe 3 0 4 . They found that the air-formed oxide film on pure iron was Fe 2 0 3 , and that anodic polarization into the passive region produced a surface film that contained Fe 3 0 4 underneath the air-formed oxide films of Fe 2 0 3 .…”

Section: Studies Of Metallic Ironmentioning

confidence: 99%

ESCA Studies of Electrode Surfaces

Sherwood

1982

Contemporary Topics in Analytical and Clinical Chemistry

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Use of differential surface charging to separate chemical differences in x-ray photoelectron spectroscopy

Havercroft

Sherwood

2000

Surf. Interface Anal.

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Differential sample charging is a potential problem in x‐ray photoelectron spectroscopic studies of insulating or partially conducting materials, especially when monochromatic x‐radiation is used. The phenomenon can be exploited to distinguish between compounds that do not exhibit a significant chemical shift but do have significant differences in sample conductivity. This paper shows how sample biasing using large d.c. negative biases can be used to identify chemical differences in an important practical system consisting of oxide films on an aluminum alloy (6061) with a significant level of contamination involving a heavily contaminated dark area and a lightly contaminated light area. The two areas exhibit significantly different spectral behavior, but in both cases differential charging assists analysis, allowing different carbon environments (disordered graphitic carbon and lubricant hydrocarbons) to be distinguished. Changes in the aluminum and magnesium core regions allow an estimate of the differences in oxide thickness to be obtained. The use of positive sample biasing to eliminate differential sample biasing is also illustrated. Copyright © 2000 John Wiley & Sons, Ltd.

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Electron Spectra of Oxide Films on Pure Iron and an Iron-Aluminium Alloy

Cited by 13 publications

References 3 publications

Oxidation Studies of Permalloy Films by Quartz Crystal Microbalance, AES, and XPS

Oxidation Studies of Permalloy Films by Quartz Crystal Microbalance, AES, and XPS

ESCA Studies of Electrode Surfaces

Use of differential surface charging to separate chemical differences in x-ray photoelectron spectroscopy

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