1980
DOI: 10.1021/ja00535a005
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Electron spectroscopic investigations of the influence of initial- and final-state effects on electronegativity

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Cited by 93 publications
(20 citation statements)
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“…Information on the energy positions of these lines for chlorine and potassium containing molecules is rather scarce, and to best of our knowledge is not available in the literature for solvated ions. [32]. The KLL Auger spectrum of aqueous Cl -has a very similar shape (see figure 2a).…”
Section: Resultsmentioning
confidence: 81%
“…Information on the energy positions of these lines for chlorine and potassium containing molecules is rather scarce, and to best of our knowledge is not available in the literature for solvated ions. [32]. The KLL Auger spectrum of aqueous Cl -has a very similar shape (see figure 2a).…”
Section: Resultsmentioning
confidence: 81%
“…The items a 0 Q and c 0 E correspond to the contribution of the initialstate effect to the substituent effect, which include two parts, a 0 Q representing the charge effect of C atom being ionized on its core ionization energy, and c 0 E representing the electrostatic effects of other atoms (nearest, next-nearest, next-next-nearest neighbors, and so on) on the C atomic core ionization energy. The item b 0 P is the contribution of the final-state effect (polarizability effect or relaxation effect) to the substituent effect [14]. In general, the amount of net partial charge on the carbon atom depends on the attracting force of the X atoms, which can be scaled by the electronegativity (such as Mulliken electronegativity) difference between the X and C atoms.…”
Section: Extension Of Slater-like Modelmentioning
confidence: 99%
“…[10] The physical meaning of Equation (2) is very clear, but the problem is how to obtain the formula to calculate DS i . To approach the evaluation of DS i , we select halomethanes (including methane and halomethane) as model compounds.…”
Section: Slater-like Modelmentioning
confidence: 99%