Electron spin resonance spectrum of the NF₂radical isolated in a neon matrix at 4°K

Why Bis(fluorosulfonyl)imide Is a “Magic Anion” for Electrochemistry

“…A field scan over a wider range reveals a group of resonance lines (radical 4 ) that correspond to a doublet ( A ∥ ( 19 F) = 197 G) of triplets ( A ∥ ( 14 N) = 42 G) that exhibits the additional doublet splitting of 8 G (Supporting Information Figure 13S). For the • NF 2 radical in solid neon, A ∥ ( 19 F) = 212 G, A ⊥ ( 19 F) ≈ 17, and A ∥ ( 14 N) = 49 G were reported, which corresponds well with our DFT estimates for gas-phase radical (Supporting Information Figure 14S and Table 3S). For • NF – radical anion, estimated hfcc’s are significantly lower ( A ∥ ( 19 F) = 142 G and A ∥ ( 14 N) = 39 G), suggesting that radical 4 is a neutral 14 N-centered radical.…”

Electron spin resonance study of nitric oxide adsorption on Linde Type Y zeolites

“…This has indeed been found to be the case for radicals such as H2C=N-9 and NF2. 10 The hyperfine coupling tensor observed with NO also falls in this category. The comparison of the coupling constant observed on Ba-Y along the y axis with that expected for a pure p orbital11 shows that the antibonding x orbital in NO contains 64% of the nitrogen 2pv orbital.…”

Derivatives of Nitrogen Fluorides

“…Various physical properties of the NF2 radical have been determined. Studies on the infrared spectrum (63, 64, 73), the ultraviolet spectrum (52, 72), the mass spectrum (23, 91), and the epr spectrum (22,40,42,64,78), as well as the group electronegativity (39), of the NF2 radical, have been determined. Some of the physical properties of tetrafluorohydrazine are presented in Table III.…”