CF3SO2F (trifluoromethanesulfonyl fluoride)
is a novel substitute to SF6. The AC breakdown tests of
pure CF3SO2F, CF3SO2F/N2, and CF3SO2F/CO2 mixtures
in a slightly non-uniform electric field were done. The effects of
pressure, electrode distance, and mixing ratio on the breakdown characteristics
of the CF3SO2F mixtures were obtained and compared
with SF6. In order to investigate the micromechanism of
dielectric properties, the structures of CF3SO2F, N2, and CO2 and their bimolecular complexes
were determined based on density functional theory (DFT). The differences
in dielectric properties between the CF3SO2F/N2 and CF3SO2F/CO2 mixtures
were analyzed. The results show that the breakdown strength of the
40%CF3SO2F/N2 and 45%CF3SO2F/CO2 mixtures are equivalent to SF6, whereas the CF3SO2F/N2 mixture
is better than the CF3SO2F/CO2 mixture.
The reason is that both the ionization energy and the enhancement
to the most easily dissociated 1S–2C chemical bond of CF3SO2F···N2 complex are
greater than those of the CF3SO2F···CO2 complex, which helps the CF3SO2F/N2 mixture to maintain a higher insulation level.