“…The radicals formed by bond homolysis of the dimers act as one electron reducing agents, reflecting the ease of electron transfer from α-carbon-centered amino acid radicals, referred to above. Reductions by the dimers of compounds such as adriamycin and daunomycin have been studied in detail, as models for the in vivo manipulation of quinone antitumor drugs. ,,,− …”
Section: Functional Group Transformationsmentioning
confidence: 99%
“…Reductions by the dimers of compounds such as adriamycin and daunomycin have been studied in detail, as models for the in vivo manipulation of quinone antitumor drugs. 240,245,246,[248][249][250][251][252][253][254][255][256][257][258] As a final example of the production of amino acid radicals through functional group transformations, photolysis of the pyrazolines 232a-c gave the corresponding cyclopropylamino acid derivatives 234a-…”
Section: Functional Group Transformationsmentioning
“…The radicals formed by bond homolysis of the dimers act as one electron reducing agents, reflecting the ease of electron transfer from α-carbon-centered amino acid radicals, referred to above. Reductions by the dimers of compounds such as adriamycin and daunomycin have been studied in detail, as models for the in vivo manipulation of quinone antitumor drugs. ,,,− …”
Section: Functional Group Transformationsmentioning
confidence: 99%
“…Reductions by the dimers of compounds such as adriamycin and daunomycin have been studied in detail, as models for the in vivo manipulation of quinone antitumor drugs. 240,245,246,[248][249][250][251][252][253][254][255][256][257][258] As a final example of the production of amino acid radicals through functional group transformations, photolysis of the pyrazolines 232a-c gave the corresponding cyclopropylamino acid derivatives 234a-…”
Section: Functional Group Transformationsmentioning
Ein Gemisch des meso‐ und dl‐Dimeren (I) des Titelradikals (II) mit dem Oxazinon (III) liefert in Methanol das über mehrere Tage beständige Radikal (IV) (ESR), das beim Erwärmen mit weiterem (II) in das Morpholinon (V) und das Oxazinon (VI) übergeht.
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