2022
DOI: 10.26434/chemrxiv-2022-k82zn-v2
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Electronegativity Equilibration

Abstract: Controlling the distribution of electrons in materials is the holy grail of chemistry and material science. Practical attempts at this feat are common but are often reliant on simplistic arguments based on electronegativity. One challenge is knowing when such arguments work, and which other factors may play a role. Ultimately, electrons move to equalize chemical potentials. In this work, we outline a theory in which chemical potentials of atoms and molecules are expressed in terms of reinterpretations of commo… Show more

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