1968
DOI: 10.1021/j100847a073
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Electronic conduction in aqueous solution

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Cited by 277 publications
(133 citation statements)
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“…NB-+ e-NB-2 (4) Two qualitative features of the voltammograms deserve comment. First, as previously reported 6 , the magnitude of the limiting current of the first reduction wave, il, decreases slightly as the concentration of NB is increased from 3.9 to 8.7 M (from 5.9 pA to 4.1 pA in Fig.…”
Section: Experimental Ptmentioning
confidence: 99%
“…NB-+ e-NB-2 (4) Two qualitative features of the voltammograms deserve comment. First, as previously reported 6 , the magnitude of the limiting current of the first reduction wave, il, decreases slightly as the concentration of NB is increased from 3.9 to 8.7 M (from 5.9 pA to 4.1 pA in Fig.…”
Section: Experimental Ptmentioning
confidence: 99%
“…When electron hopping represents the overall charge transport rate through the metallopolymer film, the DahmsRuff equation 36,37 can be used to calculate the electron selfexchange rate constant, k SE , from the D CT according to = 7 x 10 -8 molcm -2 . Analysis was performed at pH 6.0. electron transport in redox polymers, the electron selfexchange rate constant, k SE , also can be calculated as Equation 5 : …”
mentioning
confidence: 99%
“…Note that this property of diffusional leakage from a closed reservoir is universal and is the justification for the Newton general usage in such a case, we use the term 'diffusion' as it has been established that such 'site-hopping' processes give rise to the same microscopic and macroscopic laws as classical diffusion (e.g. [56][57][58][59][60][61][62][63][64][65] and Kelvin exponential laws of cooling of solid bodies. It then follows that at any time, t, the flux of catecholamine cations through the fusion pore (i.e.…”
Section: Resultsmentioning
confidence: 99%