2011
DOI: 10.1039/c1nj20240e
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Electronic structure and metal–metal communication in (CpM)2(as-indacene) and (CpM)2(s-indacene) (M = Mn, Fe, Co, Ni) complexes: a DFT investigation

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Cited by 7 publications
(2 citation statements)
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“…The ionic mono-oxidized species produced, adopt a general strategy for the synthesis of the bridged bimetallic compound from the classical methods that involve the coupling of two metallic moieties. The group 8 metallocene's, their structures, synthesis, and organometallic chemistry are widespread have been investigated for their mixedvalence properties [2][3][4][5][6][7][8].…”
Section: Introductionmentioning
confidence: 99%
“…The ionic mono-oxidized species produced, adopt a general strategy for the synthesis of the bridged bimetallic compound from the classical methods that involve the coupling of two metallic moieties. The group 8 metallocene's, their structures, synthesis, and organometallic chemistry are widespread have been investigated for their mixedvalence properties [2][3][4][5][6][7][8].…”
Section: Introductionmentioning
confidence: 99%
“…Two different molecular congurations are possible, depending on the fact that both M moieties lie on the same side of the indacenide plane (syn) or on different sides (anti). The geometry optimization of both syn and anti congurations of the homobinuclear compounds has been performed before 61 considering that the metal atoms coordinate the C 5 rings, as usually observed experimentally. [55][56][57][58] For obvious sterical reasons, [53][54][55][56][57][58] the anti conguration was always found to be slightly more stable that the syn conguration, therefore we have developed the theoretical calculations for the anti conguration.…”
Section: Dft Studiesmentioning
confidence: 99%