GrapheneāBi2Te3, a grapheneābased compound with a metal/metalloid heterostructure, is recently discovered to be a potentially novel thermoelectric material, demonstrating unprecedently enhanced thermoelectric efficiencies. The interfacial thermal transport must play an important role in determining the thermoelectric performance of this heterostructure. In particular, the interfacial thermal contact conductance (Gc) must be known in order to correctly elaborate the thermoelectric performances of grapheneāBi2Te3. Furthermore, the large nonlinear optoelectric response of this heterostructure redefines both the graphene thermal conductivity (kg) and its optical absorbance (Ag). A significantly suppressed Ag is predicted as low as 0.86% from its nominal value of 2.72% when suspended, from the transfer matrix calculations based on the Fresnel principle. Both Gc and kg are simultaneously determined from the optothermal Raman thermometry by duplexing the Raman data sets using two different objective magnifications (20Ć and 100Ć), which allows for the matching of the number of unknowns (Gc and kg) with the corresponding two Raman data sets. The thermal properties of Gc and kg for the grapheneāBi2Te3 heterostructure are first determined as 3.455 Ā± 0.619 Ć 106 W mā2 Kā1 and 440.124 Ā± 76.265 W mā1 Kā1, respectively.