Electronic Structure Modulating of W₁₈O₄₉ Nanospheres by Niobium Doping for Efficient Hydrogen Evolution Reaction

Abstract

Developing efficient electrocatalysts to reduce HER overpotential is vital to enhance hydrogen production efficiency and minimize energy consumption. Adjusting the electronic structure of transition metal oxides via elemental doping is a potent strategy to improve the effectiveness of electrocatalysts for hydrogen evolution. In this work, we synthesized a set of niobium‐doped tungsten oxides (Nbx‐W18O49) under anoxic conditions using a straightforward “one‐pot” solvothermal approach. After doping Nb, the oxygen vacancy content inside W18O49 was increased, which induced a synergistic effect with the active sites of tungsten. In acidic environments, the hydrogen evolution activity of the Nb0.6‐W18O49 electrocatalyst is second only by 20 wt% Pt/C. It attains a current density of ‐10 mA cm‐2 at an overpotential of 102 mV. By comparison with W18O49, Nb0.4‐W18O49 and Nb0.5‐W18O49, Nb0.6‐W18O49 demonstrates a reduced charge transfer resistance, which significantly enhances its conductivity and the speed of electron movement across interfaces. Coupled with this feature are notably faster HER kinetics. Additionally, it exhibits excellent stability, meaning it maintains its performance and structural integrity over prolonged periods and under various operational conditions. This article provides a new perspective for discovering inexpensive and efficient hydrogen evolution electrocatalyst materials.