2024
DOI: 10.1039/d4dt01371a
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Electrophilic As-functionalisation of σ-arsolido complexes

Ryan M. Kirk,
Anthony F. Hill

Abstract: Mononuclear-σ-arsolyl complexes of molybdenum are shown to be reactive towards electrophilic attack at arsenic, including reactions with activated alkynes which result in metallacycles rather than [4 + 2] cycloaddition to the arsolyl ring.

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