2024
DOI: 10.1021/acs.jpcb.3c08172
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Electrophoretic Mobility of Nanoparticles in Water

Dmitry V. Matyushov

Abstract: Classical equations for colloidal mobility anticipate linear proportionality between the nanoparticle mobility and zeta potential caused by the combined electrostatics of free charges at the nanoparticle and screening bound charges of the polar solvent. Polarization of the interfacial liquid, either spontaneous due to molecular asymmetry of the solvent (water) or induced by nonelectrostatic (e.g., charge-transfer) interactions, is responsible for a static interface charge adding to the overall electrokinetic c… Show more

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Cited by 3 publications
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