Electropolymerization of 2-methoxy aniline. Electrochemical and spectroscopical product characterization

Synthesis, Characterization, and Conductivity Studies of Poly-o-Methoxyaniline Intercalated into V2O5 Xerogel

“…In analogy, after the insertion and polymerization of o-methoxyaniline, the polymer is present in its doped form (p-doped), promoting the charge transport by polaronic species on the polymer backbone. Moreover, the absorption band of around 550 nm attributed to excitonic transition can be related to the charge caries responsible for the conductivity in the organic polymer (17,18,22), as shown in Fig. 4.…”

The electrochemical deposition of polyaniline at pure aluminium: electrochemical activity and corrosion protection properties

“…The degradation of polyaniline can be identified easily in cyclic voltammetry experiments by the presence of a 'middle peak' lying between the leucoemeraldine and emeraldine and the emeraldine and pernigraniline couples. This 'middle' peak has been taken as evidence for the build-up of degradation products, for film overoxidation [24], to residual oligomers trapped within the film [25] and for different polymer backbone structures arising from ortho coupling [26]. In Figs.…”

Electrochemical preparation and kinetic study of poly(o-tolidine) in aqueous medium

“…While the electropolymerization of mononuclear aromatic amines has received a great deal of attention [8][9][10][11], the electropolymerization of the polynuclear aromatic amines, especially polynuclear compounds with two NH 2 groups, has got much less attention. Polynuclear amines containing one NH 2 group such as 1-amino-9,10-anthraquinone [6,7], 5-amino-1-naphthol [12], 1-naphthylamine [13] or two NH 2 groups such as benzidine [14], 1,5-diaminonaphthalene [15], has been used for preparation of polymeric film coated electrodes.…”